Head gasket or cracked head, could be a bad rad cap.......long shot, lol
Refill with water don't waste money on coolant.
Leave rad cap off and start cold engine
If coolant starts coming out of rad cap opening...........bad news.
If you have to pay for a Block test(hydro carbon test) don't, just do the Glove test, it's free and better because you can ID which cylinder has the leak.